Ing. Michael Fridrich

Recycling spent lithium-ion batteries (LIBs) is critical for enhancing environmental sustainability and resource conservation; however, the environmental and energy impacts of LIB recycling are not yet comprehensively understood due to the diverse applications of LIB cells and the variability in recycling technologies. This study presents a gate-to-gate life cycle assessment (LCA) of a recycling pre-treatment process at a small-scale plant in the Czech Republic, focusing on spent LIBs from electric vehicles (EVs) and consumer electronics cells (CECs). Using the SimaPro LCA software and the Ecoinvent 3.9 database, the analysis evaluated the environmental impact of recycling operations across several categories, including climate change, eutrophication, freshwater, and resource use, minerals and metals. The findings reveal that the recycling pre-treatment process for CECs achieves greater benefits in climate change mitigation compared to EV batteries, with a 5% lower impact for climate change associated with EV batteries relative to CECs. Moreover, the study highlights the effectiveness of optimized recycling practices in alleviating environmental burdens. A notable finding is the significance of secondary material recovery, particularly metals such as copper and aluminium, as these materials can substitute for primary raw materials, thereby minimizing resource use and reducing emissions. These aspects emphasize the need for high recovery efficiency to enhance environmental benefits. However, further research is essential to fully comprehend the environmental impacts of LIB recycling and to resolve uncertainties concerning battery composition and the effectiveness of different recycling technologies.

The significant deployment of lithium-ion batteries (LIBs) within a wide application field covering small consumer electronics, light and heavy means of transport, such as e-bikes, e-scooters, and electric vehicles (EVs), or energy storage stationary systems will inevitably lead to generating notable amounts of spent batteries in the coming years. Considering the environmental perspective, material resource sustainability, and terms of the circular economy, recycling represents a highly prospective strategy for LIB end-of-life (EOL) management. In contrast with traditional, large-scale, implemented recycling methods, such as pyrometallurgy or hydrometallurgy, direct recycling technology constitutes a promising solution for LIB EOL treatment with outstanding environmental benefits, including reduction of energy consumption and emission footprint, and weighty economic viability. This work comprehensively assesses the limitations and challenges of state-of-the-art, implemented direct recycling methods for spent LIB cathode and anode material treatment. The introduced approaches include solid-state sintering, electrochemical relithiation in organic and aqueous electrolytes, and ionothermal, solution, and eutectic relithiation methods. Since most direct recycling techniques are still being developed and implemented primarily on a laboratory scale, this review identifies and discusses potential areas for optimization to facilitate forthcoming large-scale industrial implementation.

This study presents a comprehensive cradle-to-gate Life Cycle Assessment of fuel cell electric vehicles (FCEVs), providing a comparative assessment against alternative and fossil fuel-driven counterparts. The research focuses on hydrogen as a fuel source, emphasizing two key production methods: natural gas reforming and water electrolysis. The scope of the study is set to the Czech Republic environment. Diverse sources of electric generation, such as wind and photovoltaics, are considered to supply the electrolysis process. The energy source mix predictions are set to year 2030 up to 2050. The feasibility of transitioning towards greater utilization of renewable energy sources within the context of privately owned vehicles is investigated in this work. Specifically, the study examines the exact part of the vehicle life cycle, starting with production to the use phase, with a consideration of the car’s lifetime, aiming to provide a nuanced understanding of their environmental footprint and clear comparability with each other. This study highlights the significant potential for reducing the environmental impacts of personal vehicles through the usage of hydrogen. With FCEVs emitting zero direct emissions, the total environmental impact is directly tied to the process of fuel production. Producing hydrogen through electrolysis, particularly when powered by photovoltaic or wind energy can significantly lower its emissions, especially in terms of greenhouse gas emissions.

Recycling lithium-ion batteries (LIBs) have become increasingly important in response to expanding electromobility. This paper is focused on evaluating the environmental impacts (EIs) of recycling pre-treatment of three types of LIBs with black mass as its product. A detailed gate-to-gate Life Cycle Assessment study was conducted to obtain EIs of the recycling process. The benefits of LIBs recycling pre-treatment and significant recovery of secondary aluminum for compared battery types are highlighted in the analysis. This paper points out that the varying chemistry of the compared LIBs does not affect the resulting EIs of the recycling pre-treatment procedures.